After going head-to-head with Natalie, Paul got back on track as he knocked out the next two players.
This meant his opponent faced the Final Chase on her own and was hoping she could do enough to walk away with £4,000.
However, the Chaser seemed too knowledgable for her as he managed to topple her with 44 seconds to spare.
Commencing her efforts, The Sinnerman said: “Natalie, you did yourself proud. No regrets on your part.”
The Chase airs weekdays at 5pm on ITV.